The Lindemann Theory of Unimolecular Reactions

[ Also known as Lindemann-Hinshelwood mechanism. ] It is easy to understand a bimolecular reaction on the basis of collision theory. When two molecules A and B collide, their relative kinetic energy exceeds the threshold energy with the result that the collision results in the breaking of comes and the formation of new bonds. But how can one account for a unimolecular reaction? If we assume that in such a reaction $ A \longrightarrow P $ , the molecule A…

Cvraman

Raman Effect- Raman Spectroscopy- Raman Scattering

In contrast to other conventional branches of spectroscopy, Raman spectroscopy deals with the scattering of light & not with its absorption. Raman Effect Chandrasekhar Venkat Raman discovered in 1928 that if light of a definite frequency is passed through any substance in gaseous, liquid or solid state, the light scattered at right angles contains radiations not only of the original frequency (Rayleigh Scattering)  but also of some other frequencies which are generally lower but occasionally higher than the frequency of the incident light. The phenomenon of scattering of light by a…